Vents98 Leg 4 Readme File Ship: NOAA research vessel Ronald H. Brown Cruise Start: Victoria, BC, Canada, September 23, 1998 Cruise End: Seattle, WA, October 3, 1998 Chief Scientist: Hugh Milburn System Operator: Marilyn Roberts Expocode: 33RO19980923 Method: Infrared absorption of dry gas. Measurement of fugacity of Carbon Dioxide in surface water and air using continuous sampling methods. See Wanninkhof and Thoning, 1993 in Marine Chemistry, 44, 189-205 for details of the system. Standard gases come from CMDL in Boulder and are directly traceable to the WMO scale. Sampling Cycle: The system runs on an hourly cycle during which 3 standard gases, 3 air samples from the bow tower and 8 surface water samples (from the equilibrator head space) are analyzed on the following schedule: Mins. after hour Sample 4 Low Standard 8 Mid Standard 12 High Standard 16.5 Water 21 Water 25.5 Water 30 Water 34 Air 38 Air 42 Air 46.5 Water 51 Water 55.5 Water 60 Water Units: All xCO2 values are reported in parts per million (ppm) and fCO2 values are reported in microatmospheres (uatm). Notes for Leg 4: 1. The ship's salinity sensor began giving erratic readings near the end of the previous leg. By the end of leg 3, the readings settled down. However, the offset between the YSI TSG attached to our system and the ship's TSG changed. For most of leg 3 the YSI gave readings about 0.15 higher than the ship's TSG. From near the end of leg 3 and for all of leg 4, the YSI read about 0.07 lower than the ship's TSG. I have left the ship's salinity values as they were recorded and used them to compute fCO2, etc for this leg. 2. Problems with the PC clock and the feed from the ship's computer system resulted in the loss of about 2-1/2 hour's worth of data at the beginning of leg 4 (from 267.014 through 267.109). Dec. 12, 2000: 3. Starting on Oct. 1 the lat and lon from the ship's computer system included only 3 significant digits. I fixed this by interpolating latitude and longitude values. For questions or comments contact: Bob Castle 4301 Rickenbacker Causeway Miami, FL 33149 305-361-4418 castle@aoml.noaa.gov