RB-08-07 TAO-NDBC Readme File Ship: NOAA research vessel Ronald H. Brown Cruise Start: Arica, Chile, Dec. 10, 2008 Cruise End: Rodman, Panama, Jan. 11, 2009 Chief Scientists: William Wells System Operator: Jonathan Shannahoff Expocode: 33RO20081210 Method: The system was built by General Oceanics (GO) and is described in Pierrot, et al. (2009) The three standard gases come from CMDL in Boulder and are directly traceable to the WMO scale. Sampling Cycle: The system runs on an cycle during which 3 standard gases, 5 air samples from the bow tower and 50 surface water samples (from the equilibrator head space) are analyzed on the following schedule: 1. Zero and span of Licor 2. Three standard gases 3. Five air samples 4. Fifty equilibrator headspace gas samples 5. Repeat steps 2 - 4 nine more times 6. Restart from step 1 Standards: CA6709: 284.75 ppm, CA2813: 363.24 ppm, CA9721: 432.57 ppm, CA7931: 545.88 ppm. Units: All xCO2 values are reported in parts per million (ppm) and fCO2 values are reported in microatmospheres (uatm) assuming 100 % humidity at the equilibrator temperature. Notes: 1. Any values outside the range of the standards (284.75 to 545.88 ppm) have been flagged as 3 and should be considered approximate (within 5 ppm). While individual data points above 545 or below 285 may not be accurate, the general trends should be indicative of the seawater chemistry. 2. Salinity readings from the ship's TSG were bad. Readings from the Seabird Micro TSG connected to the analytical system were used instead. 3. An offset of 2.75 minutes was applied to SST data from the ship's computer system. 4. Due to a system malfunction no data was collected before Dec. 19 at 19:55. 5. The system was shut down on Dec. 22 at 13:51. When it was restarted at 19:54, the GPS was not working. The system ran until Jan. 2 at 19:47 with no data from the GPs. It was then stopped and restarted 5 minutes later with the GPs working. During the period when the GPS was down, latitude and longitude data from the ship's computer system have been merged into the system data file. For questions or comments contact: Bob Castle 4301 Rickenbacker Causeway Miami, FL 33149 305-361-4418 robert.castle@noaa.gov