RB-08-06A Stratus/Vocals1 Readme File Ship: NOAA research vessel Ronald H. Brown Cruise Start: Rodman, Panama, Oct. 14, 2008 Cruise End: Arica, Chile, Nov. 3, 2008 Chief Scientists: Bob Weller System Operator: Jonathan Shannahoff Expocode: 33RO20081014 Method: The system was built by General Oceanics (GO) and is described in Pierrot, et al. (2009) The three standard gases come from CMDL in Boulder and are directly traceable to the WMO scale. Sampling Cycle: The system runs on an cycle during which 3 standard gases, 5 air samples from the bow tower and 50 surface water samples (from the equilibrator head space) are analyzed on the following schedule: 1. Zero and span of Licor 2. Three standard gases 3. Five air samples 4. Fifty equilibrator headspace gas samples 5. Repeat steps 2 - 4 nine more times 6. Restart from step 1 Standards: CA6709: 284.75 ppm, CA2813: 363.24 ppm, CA9721: 432.57 ppm, CA7931: 545.88 ppm. Units: All xCO2 values are reported in parts per million (ppm) and fCO2 values are reported in microatmospheres (uatm) assuming 100 % humidity at the equilibrator temperature. Notes: 1. Any values outside the range of the standards (284.75 to 545.88 ppm) have been flagged as 3 and should be considered approximate (within 5 ppm). While individual data points above 545 or below 285 may not be accurate, the general trends should be indicative of the seawater chemistry. 2. Salinity readings from the ship's TSG were bad. Readings from the Seabird Micro TSG connected to the analytical system were used instead. 3. There were propulsion (Z-drive) problems that required interruption of this cruise. The ship left Panama on 14 Oct, sailed ~SW for ~day, and then returned to Panama for repairs. During this first interval, the CO2 system performed fine though the SCS data were not recorded - there was no direct SST measurements. The ship left Panama a day later (18 Oct, YD 292), but the GPS as well as the SCS data were not being recorded. The GPS positions were recorded starting at 15:00 on 20 Oct (YD 294.62) and the SCS data were recorded starting at 10:00 on 21 Oct (YD 295.42). The first submission of data for this cruise only included analyses that had SCS data. The resubmission includes some new raw data files plus all of the data initially submitted. With the resubmission of data, the ExpoCode associated with the cruise was adjusted to cover the new data at the start of the cruise. For the analyses with SCS data, a 1.65min time offset between the Equ and SBE21 Temperatures was determined, which was the transit time between the inlet and seawater pump and the equilibrator. A 0.226 (+/-0.056) degree Celsius temperature offset between the equilibrator and time-shifted SST (YD 296.5 - 308) was calculated. The equilibrator temperatures were warmer. For the analyses without SCS data, the SST values were estimated by subtracting 0.226 degree from the equilibrator temperatures. Original Data Location: http://www.aoml.noaa.gov/ocd/ocdweb/brown/brown_introduction.html For questions or comments contact: Kevin Sullivan 4301 Rickenbacker Causeway Miami, FL 33149 305-361-4382 kevin.sullivan@noaa.gov