Gasex98 Leg 3 Readme File Ship: NOAA research vessel Ronald H. Brown Cruise Start: Punta Del Gado, Azores, June 28, 1998 Cruise End: Miami, FL, July 7, 1998 Chief Scientist: Shari Yvon-Lewis System Operator: Craig Neill Expocode: 33RO19980628 Method: Infrared absorption of dried gas. For details of the system see: Measurement of fugacity of Carbon Dioxide in surface water and air using continuous sampling methods. Wanninkhof and Thoning, 1993 in Marine Chemistry 44, 189-205, And: Feely, R.A., R. Wanninkhof, H.B. Milburn, C.E. Cosca, M. Stapp, and P.P. Murphy, A new automated underway system for making high precision pCO2 measurements onboard research ships, Analytica Chim. Acta, 377, 185-191, 1998. The three standard gases come from CMDL in Boulder and are directly traceable to the WMO scale. Sampling Cycle: The system runs on an hourly cycle during which 3 standard gases, 3 air samples from the bow tower and 8 surface water samples (from the equilibrator head space) are analyzed on the following schedule: Mins. after hour Sample 4 Low Standard 8 Mid Standard 12 High Standard 16.5 Water 21 Water 25.5 Water 30 Water 34 Air 38 Air 42 Air 46.5 Water 51 Water 55.5 Water 60 Water Units: All xCO2 values are reported in parts per million (ppm) and fCO2 values are reported in microatmospheres (uatm) assuming 100 % humidity at the equilibrator temperature. Notes for Leg 3: 1. Gas flow in the water phase was low (but adequate) until June 30 @ 1100 GMT. 2. On July 3 from 0230 to 0330 the system was down due to a power failure. 3. On July 5 at 1545 GMT the standard tanks were changed from 275.63=Low, 297.74=Mid, & 360.62=High to 297.74=Low, 360.62=Mid, & 408.35=High. For questions or comments contact: Bob Castle 4301 Rickenbacker Causeway Miami, FL 33149 305-361-4418 castle@aoml.noaa.gov