Gasex98 Leg 2 Readme File Ship: NOAA research vessel Ronald H. Brown Cruise Start: Lisbon, Portugal, May 25, 1998 Cruise End: Punta Del Gado, Azores, June 26, 1998 Chief Scientist: Rik Wanninkhof System Operator: Bob Castle Expocode: 33RO19980525 Method: Infrared absorption of dried gas. For details of the system see: Measurement of fugacity of Carbon Dioxide in surface water and air using continuous sampling methods. Wanninkhof and Thoning, 1993 in Marine Chemistry 44, 189-205, And: Feely, R.A., R. Wanninkhof, H.B. Milburn, C.E. Cosca, M. Stapp, and P.P. Murphy, A new automated underway system for making high precision pCO2 measurements onboard research ships, Analytica Chim. Acta, 377, 185-191, 1998. The three standard gases come from CMDL in Boulder and are directly traceable to the WMO scale. Sampling Cycle: The system runs on an hourly cycle during which 3 standard gases, 3 air samples from the bow tower and 8 surface water samples (from the equilibrator head space) are analyzed on the following schedule: Mins. after hour Sample 4 Low Standard 8 Mid Standard 12 High Standard 16.5 Water 21 Water 25.5 Water 30 Water 34 Air 38 Air 42 Air 46.5 Water 51 Water 55.5 Water 60 Water Units: All xCO2 values are reported in parts per million (ppm) and fCO2 values are reported in microatmospheres (uatm) assuming 100 % humidity at the equilibrator temperature. Notes for Leg 2: 1. On May 29 some small air leaks in the system were discovered and repaired. Data prior to 2030 GMT shows higher variability than normal. 2. On May 30 from 2330 to 2400 GMT positive pressure in equilibrator caused headspace gas to back up into the Licor sample cell, resulting in bad readings. 3. On May 31 from 2115 to 2300 GMT the system was down to install a solenoid valve on the sample output of the Licor. 4. On June 3 from 1412 to 1825 the system was down to recalibrate the YSI TSG. 5. On June 9 from 545 to 625 the system was down to clean the equilibrator's shower head. 6. On June 12 from 1225 to 1312 the system was down to install a bounceless switch on the Valco valve. 7. On June 12 from 1430 to 1600 the system was down to recalibrate the YSI O2 sensor. 8. On June 17 from 1505 to 1930 the system was down to recalibrate the YSI O2 sensor. 9. On June 25 from 1315 to 1640 the system hung due to operator error. For questions or comments contact: Bob Castle 4301 Rickenbacker Causeway Miami, FL 33149 305-361-4418 castle@aoml.noaa.gov