Tsunami Vents 2000 Readme File Ship: NOAA research vessel Ronald H. Brown Cruise Start: Seattle, Wa, March 17, 2000 Cruise End: Newport, Or, March 22, 2000 Chief Scientist: Scott Stalin System Operator: Bob Castle Expocode: 33RO20000318 Method: Infrared absorption of dried gas. For details of the system see: Measurement of fugacity of Carbon Dioxide in surface water and air using continuous sampling methods. Wanninkhof and Thoning, 1993 in Marine Chemistry 44, 189-205, And: Feely, R.A., R. Wanninkhof, H.B. Milburn, C.E. Cosca, M. Stapp, and P.P. Murphy, A new automated underway system for making high precision pCO2 measurements onboard research ships, Analytica Chim. Acta, 377, 185-191, 1998. The three standard gases come from CMDL in Boulder and are directly traceable to the WMO scale. Sampling Cycle: The system runs on an hourly cycle during which 3 standard gases, 3 air samples from the bow tower and 8 surface water samples (from the equilibrator head space) are analyzed on the following schedule: Mins. after hour Sample 4 Low Standard 8 Mid Standard 12 High Standard 16.5 Water 21 Water 25.5 Water 30 Water 34 Air 38 Air 42 Air 46.5 Water 51 Water 55.5 Water 60 Water Units: All xCO2 values are reported in parts per million (ppm) and fCO2 values are reported in microatmospheres (uatm) assuming 100 % humidity at the equilibrator temperature. Notes: 1. A new system (System 2.6, replacing System 2.5) was used on this cruise for the first time. Side-by-side tests in the lab show the average difference in computed concentration for the two systems to average 0.2723 ppm with a standard deviation of 0.43575 (n = 289). The main difference between the two systems is that an improved temperature control system for the Licor analyzer has been introduced in System 2.6. For further details contact Bob Castle (see address at the end of this file). 2. Water values before March 18 at 1900 GMT were removed due to high variability in the readings. This was caused by air leaks in the water lines. 3. The system was down from 2130 GMT on March 18 to 0300 GMT on March 19 except for 1/2 hour while work was done on the plumbing connections. 4. The system was down from 2015 GMT to 2358 on March 20 for software modifications. 5. Data from 2045 GMT to 2400 on March 21 was discarded because system work corrupted the readings. 6. The system was down from 0430 to 0500 GMT on March 22 to replace a tube in the equilibrator. For questions or comments contact: Bob Castle 4301 Rickenbacker Causeway Miami, FL 33149 305-361-4418 castle@aoml.noaa.gov