RB-03-04A
CO2/CLIVAR Cruise (WOCE A16N) Leg A Readme File

Ship:				NOAA research vessel Ronald H. Brown
Cruise Start:		Charleston, SC, June 5, 2003
Cruise End:			Reykjavik, Iceland, June 14, 2003
Chief Scientist:	Kevin Sullivan
System Operator:	Jonathan Shannahoff
Expocode:               33RO20030605

Method:
Infrared absorption of dried gas.  For details of the system see: 
Measurement of fugacity of Carbon Dioxide in surface water and air using continuous 
sampling methods.  Wanninkhof and Thoning, 1993 in Marine Chemistry 44, 189-205, 
And:
Feely, R.A., R. Wanninkhof, H.B. Milburn, C.E. Cosca, M. Stapp, and P.P. Murphy, 
A new automated underway system for making high precision pCO2 measurements 
onboard research ships, Analytica Chim. Acta, 377, 185-191, 1998.

The three standard gases come from CMDL in Boulder and are directly traceable to 
the WMO scale.

Sampling Cycle:
The system runs on an hourly cycle during which 3 standard gases, 3 air 
samples from the bow tower and 8 surface water samples (from the 
equilibrator head space) are analyzed on the following schedule:

Mins. after hour		Sample
4				Low Standard
8				Mid Standard
12				High Standard
16.5			Water
21				Water
25.5			Water
30				Water
34				Air
38				Air
42				Air
46.5			Water
51				Water
55.5			Water
60				Water

Units:
All xCO2 values are reported in parts per million (ppm) and fCO2 values 
are reported in microatmospheres (uatm) assuming 100 % humidity at the 
equilibrator temperature.

Notes:
1.	Any values outside the range of the standards (295.37, 357.18, & 423.28 ppm) 
should be considered approximate (within 5 ppm).  While individual data points above 
423 or below 293 may not be accurate, the general trends should be indicative of the seawater 
chemistry.
2.  Seawater was turned off from June 7 @ 0950 to June 10 @ 2250 and from June
11 @ 1354 to June 12 @ 1720 (GMT) because no permission had been given to sample in
Canadian and Danish waters respectively.
3.  Early in the cruise air values that differed significantly from the baseline value of
approximately 378 ppm were recorded.  I believe these are caused by air from the North
American continent and are real, so I have left them in and given them a QC flag of 3.


For questions or comments contact:
Bob Castle
4301 Rickenbacker Causeway
Miami, FL 33149
305-361-4418
robert.castle@noaa.gov